CHEMISTLAB

ChemistLab for « Catalyse Homogène pour la préparation d’Elastomères : MécanIsmes et SynThèse » is a joint laboratory between academic institutions (CNRS, UCBL, CPE, INSA) and the Manufacture Française des Pneumatiques Michelin.

The laboratory of Catalysis, Polymerization, Processes and Materials (UMR 5128), the Institute for Molecular and Supramolecular Chemistry and Biochemistry (UMR 5246) and Michelin have federated via the creation of a joint laboratory, around a research program oriented towards the design of advanced elastomers by polymerization catalysis and meeting the criteria of the Michelin Group's circular economy strategy (Renew, Reduce, Recycle, Reuse).

This interdisciplinary laboratory masters a global chain of competences combining chemistry and reaction engineering to design, synthesize and evaluate the physicochemical and mechanical properties of new elastomers.

 

Eric Le Roux / Université Claude Bernard Lyon 1

 

Publications :

« Design of selective divalent chain transfer agents for coordinative chain transfer polymerization of ethylene and its copolymerization with butadiene » N. Baulu, M.-N. Poradowski, L. Verrieux, J. Thuilliez, F. Jean-Baptiste-dit-Dominique, L. Perrin, F. D’Agosto, and C. Boisson, Polym. Chem. 2022, 13, 1970-1977. DOI: 10.1039/d2py00155a.

« Switch from Anionic Polymerization to Coordinative Chain Transfer Polymerization: a Valuable Strategy to Make Olefin Block Copolymers » N. Baulu, M. Langlais, R. Ngo, J. Thuilliez, F. Jean-Baptiste-dit-Dominique, F. D’Agosto, and C. Boisson, Angew. Chem. Int. Ed. 2022, 61, e202204249. DOI: 10.1002/anie.202204249.

« Ethylene Coordinative Chain Transfer Polymerization-Induced Self-Assembly (CCTPISA) » N. Baulu, M. Langlais, P.-Y. Dugas, J. Thuilliez, F. Jean-Baptiste-dit Dominique, M Lansalot, C. Boisson, and F. D'Agosto, Chem. Eur. J. 2022, e202202089. DOI: 10.1002/chem.202202089.

« Cationic Phenoxyimine Complexes of Yttrium: Synthesis, Characterization, and Living Polymerization of Isoprene » A. D. Oswald, L. Verrieux, P.-A. R. Breuil, H. Olivier-Bourbigou, J. Thuilliez, F. Vaultier, M. Taoufik, L. Perrin, and C. Boisson, Organometallics 2022, 41, 2106−2118. DOI: 10.1021/acs.organomet.2c00238.

« Monocationic Bis-Alkyl and Bis-Allyl Yttrium Complexes: Synthesis, 89Y NMR Characterization, Ethylene or Isoprene Polymerization, and Modeling » A. D. Oswald, A. El Bouhali, E. Chefdeville, P.-A. R. Breuil, H. Olivier-Bourbigou, J. Thuilliez, F. Vaultier, A. De Mallmann, M. Taoufik, L. Perrin, C. Boisson, Organometallics 2021, 40, 218-230

« Les polyoléfines, What else?» V. Monteil, C. Boisson, Actualité Chimique 2020-2021, n° 456-457-458.

« Ene/Diene Copolymerization Catalyzed by Cationic Sc and Gd d0 Metal Complexes: Speciation, Ion Pairing, and Selectivity from a Computational Perspective » L. Verrieux, J. Thuilliez, F. Jean-Baptiste-dit-Dominique, C. Boisson, M.-N. Poradowski, L. Perrin, ACS Catal. 2020, 10, 12359-12369. DOI: 10.1021/acscatal.0c02657.

« Identification of a transient but key motif in the living coordinative chain transfer cyclo-copolymerization of ethylene with butadiene » I. Belaid, B. Macqueron, M.-N. Poradowski, S. Bouaouli, J. Thuilliez, F. Da Cruz-Boisson, V. Monteil, F. D'Agosto, L. Perrin, C. Boisson, ACS Catal. 2019, 9, 9298-9309. DOI: 10.1021/acscatal.9b02620.

 

Published patents :

FR2012206, PCT/FR2021/052058 (22/11/2021), WO2022112699. E. Moreso, J. Thuilliez, F. Jean-Baptiste-dit-Dominique, N. Baulu, D. Montarnal, F. D’Agosto, C. Boisson.

FR2012207, PCT/FR2021/052059 (22/11/2021), WO2022112700. R. Ngo, J. Thuilliez, F. Jean-Baptiste-dit-Dominique, N. Baulu, F. D’Agosto, C. Boisson.

FR2012077, PCT/FR2021/052043 (19/11/2021), WO2022112690. R. Ngo, J. Thuilliez, F. Jean-Baptiste-dit-Dominique, N. Baulu, F. D’Agosto, C. Boisson

FR2012078, PCT/FR2021/052044 (19/11/2021), WO2022112691. R. Ngo, J. Thuilliez, F. Jean-Baptiste-dit-Dominique, N. Baulu, F. D’Agosto, C. Boisson

FR2012080, PCT/FR2021/052045 (19/11/2021), WO2022112692. CNRS, CPE-Lyon et Université Claude Bernard Lyon 1, Michelin. R. Ngo, J. Thuilliez, F. Jean-Baptiste-dit-Dominique, N. Baulu, F. D’Agosto, C. Boisson.

FR2012083, PCT/FR2021/052046 (19/11/2021), WO2022112693. CNRS, CPE-Lyon et Université Claude Bernard Lyon 1, Michelin. R. Ngo, J. Thuilliez, F. Jean-Baptiste-dit-Dominique, N. Baulu, F. D’Agosto, C. Boisson.

FR2011890 (FR3116277). R. Ngo, J. Thuilliez, V. Lafaquière, F. Jean-Baptiste-dit-Dominique, N. Baulu, F. D’Agosto, C. Boisson.

FR2011886, PCT/FR2021/051973 (08/11/2021), WO2022106769. CNRS, CPE-Lyon et Université Claude Bernard Lyon 1, Michelin. R. Ngo, J. Thuilliez, V. Lafaquière, F. Jean-Baptiste-dit-Dominique, N. Baulu, F. D’Agosto, C. Boisson.

FR1909032, PCT/FR2020/051381 (27/07/2020) WO2021023924. CNRS, CPE-Lyon et Université Claude Bernard Lyon 1, Michelin. E. Moreso, J. Thuilliez, F. Jean-Baptiste-Dit-Dominique, C. Boisson, F. D’Agosto, N. Baulu, D. Montarnal

 

Invited conferences and scientific events :

Advances in Polyolefins 2022 (Rohnert Park (USA), septembre 2022)

« Design of Olefin block Copolymers from Coordinative Chain transfer (co)polymerization of ethylene and butadiene »

C. Boisson, F. D’Agosto, D. Montarnal, N. Baulu, M. Langlais, S. Alioui, L. Perrin, M.-N. Poradowski, F. Jean-Baptiste-dit-Dominique, J. Thuilliez, R. Ngo, C. Dire

 

ACS Spring 2020-Advances in functionalization of polyolefins (Philadelphia (USA), 22-27 March 2020).

« Controlled radical and coordination-insertion polymerizations of ethylene for the production of block copolymers »

A. Wolpers, C. Bergerbit, F. Baffie, V. Monteil, M. Lansalot, N. Baulu, C. Boisson, F. D’Agosto

 

ACS National Meeting (17 au 20 Août 2020 - Virtual Event)

« Copolymerization of ethylene with butadiene, a success story »

C. Boisson, V. Monteil, F. D’Agosto, L. Perrin, E. Moreso, F. Jean-Baptiste dit Dominique, J. Thuilliez

 

Blue Sky Conferences on Catalytic Olefin Polymerization (24 au 28 Juin 2019 –Naples - Italie)

« Neodymium catalysts for new polyolefin materials: chain shuttling and copolymerization of ethylene with conjugated dienes »

L. Perrin, F. D’Agosto, C. Boisson

 

 

 

Seminar of the joint laboratory ChemistLab at Clos des Varennes in Chazay D'Azergues (May 24, 2022).

 

On parle de nous :

 

Entre Michelin et le CNRS, une belle histoire de recherche et de coopération -  CNRS Lettre de l'innovation 15/09/2022

Scientific awards:

Christophe BOISSON, Directeur de Recherche at CP2M was awarded the 2022 Aymé Poirson award by the Académie des sciences française.

https://www.academie-sciences.fr/fr/Laureats/laureats-2022-des-prix-thematiques.html#poirson

 

Members :

Director : Christophe Boisson – Co-director : François Jean-Baptiste-dit-Dominique

 

LABORATORIES :

Lionel PERRIN            ICBMS

Pierre-Adrien PAYARD ICBMS

Christophe BOISSON  CP2M

Vincent MONTEIL       CP2M

Franck D'AGOSTO      CP2M

Damien MONTARNAL CP2M

Jean RAYNAUD          CP2M

Mostafa TAOUFIK       CP2M

Olivier BOYRON         CP2M

Sébastien NORSIC     CP2M

Kai SZETO                 CP2M

 

MICHELIN :

Florent VAULTIER

Marie-Noëlle PORADOWSKI

Charlotte DIRE

François JEAN-BAPTISTE-DIT-DOMINIQUE

Severin DRONET

Robert NGO

Philip-Christopher GEORGES

Thibaut SOUCHARD

 

PhD students and Post-doctoral fellows :

Ms. Ariane DESGRANGES

Ms. Ludmilla VERRIEUX

M. Nicolas HALL

M. Samy ALIOUI

Dr. Marvin LANGLAIS

Ms. Mariam NAHRA